Your DHCP addresses start at 192.168.1.100 and probably go to 192.168.1.125 so I would choose an address outside that range and outside the gateway address zone, say 192.168.1.25 or even 192.168.1.170 as both are unlikely to conflict with anything.
The term most use for a non-DHCP address is a static address/reserved address.
Your NAS should be assigned a static address as well.





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